The corrosion assisted stress crack growth rate of 304l stainless steel welds, was determined by the rising displacement test method. Known microstructural parameters such as ferrite phase fraction seems to play a significant role in crack propagation. Primary water stress corrosion cracking pwscc in bimetal. One significant concern for the structural integrity is stress corrosion cracking scc in the heat affected zone of welds in the stainless steel canister that confines the spent fuel.
Development of a procedure for the ultrasonic examination. We hereby report a simple surface engineering technique to make aisi grade 321 stainless steel ss welds resistant to stress corrosion cracking scc in chloride environment. Ferrite phase fraction quantification in stress corrosion. Stress corrosion cracking crack growth behavior of type. Another way in which welding can affect the corrosion resistance of stainless steels is by introducing conditions that can lead to stress corrosion cracking. Stress corrosion behavior of stainless steel welds in high. The corrosion resistance of stainless steels depends on a protective. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation.
Stress corrosion cracking of type 304l stainless steel. Kim 1 massachusetts institute of technology, plasma science and fusion center, 185 albany st. Abstract micro structural analyses by several advanced metallographic techniques were conducted on austenitic stainless steel mockup and core shroud welds that cracked in boiling water reactors. The effect of microstructural changes in 304 austenitic stainless steel induced by the processes of gas tungsten arc welding gtaw and laserbeam welding lbw on the pitting and stress corrosion cracking scc behaviors was investigated. In this study, er electrode rod 308l was utilized as the filler metal for the groove and overlay welds of a 304l stainless steel substrate, which. It can occur even in metals which are known to fail generally by ductile fracture that is true especially at elevated temperatures, if subjected to a tensile stress in a corrosive environment scc is highly chemically specific certain alloys are likely to undergo this kind of failure only when exposed to a small. Stress corrosion cracks at the weld toe of the welded pipe. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion cracking scc in type 316 l lowcarbon austenitic stainless steel recirculation pipes have been observed near buttwelding joints. Stresscorrosioncracking scc is the unexpected sudden brittle failure. Raja corrosion science and engineering, indian institute of technology, mumbai 400 076, india abstract this paper concerns with the e. Although austenitic stainless steels possess excellent resistance to general corrosion, they are susceptible to the localized corrosive attacks, such as pitting corrosion, intergranular corrosion and stress corrosion cracking scc, in chloridecontaining environments.
This paper presents a fusion welding process that was developed for snf canister repair. For a better understanding toward stress corrosion cracking scc in dissimilar metal welds with 304l stainless steel and alloy 82, the scc growth behavior in the transition regions of weld joints. These scc in type 316 l stainless steel grow near the welding zone mainly because of the high tensile residual stress caused by welding. Stress corrosion cracking susceptibility of dissimilar. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack. Removal and prevention of rust on stainless steel welds. Contrary to previous beliefs, heataffected zones of t. The potential for stress corrosion cracking scc of welded stainlesssteel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. Although useful, this process can seriously damage the anticorrosive. In part 1, t g gooch described a study of effects of nickel on the stress corrosion cracking behaviour of weld metals appropriate to structural and pipeline steels, in which tests were carried out using nickelfree and nickel containing electrodes, and electrodes without.
It is necessary to continue the research to determine the relationship betweenwelding parameters, obtained structures, and corrosion resistance of dissimilar stainless steels welded joints. Caustic stress corrosion cracking inspectioneering. Sensor requirements for detection and characterization of. Basic understanding of weld corrosion corrosion failures of welds. What causes stress corrosion cracking in pipelines. The effect of ferrite content on stress corrosion cracking. These observations, combined with previous reports on the strong influence of weld flux, indicate that oxygen and fluorine contamination and fluorinecatalyzed stress corrosion play a major role in cracking of type 304l stainless steel core shroud welds. Paul woollin twi ltd, granta park, great abington, cambridge, cb1 6al, uk. Development of stress corrosion cracking resistant welds of 321. We hereby report a simple surface engineering technique to make aisi grade 321 stainless steel ss welds resistant to stress corrosion cracking scc in. Stress corrosion cracking resistance of super 304h stainless steel was deteriorated by gta welding due to the formation of susceptible microstructure in the haz. The cracking, mainly confined to the inconel weld metal, is caused by corrosion mechanisms. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
Stress corrosion cracking crack growth behavior of type 316l stainless steel weld metals in boiling water reactor environments j. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing. The stress concentration of the butt joint is mainly caused by the weld height, and the weld of the butt joint has the greatest stress at the weld toe. Stress corrosion cracking behaviour of gas tungsten arc welded. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2 at above about 100c. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Although austenitic stainless steels possess excellent resistance to. Therefore quantifying ferrite phase fraction is an important step in ensuring weld quality. Tensile weld residual stresses, in addition to service loads, contribute to pwscc primary. We hereby report a simple surface engineering technique to make aisi grade 321 stainless steel ss welds resistant to stress corrosion. Pdf on jan 1, 2004, bertrand hoerner and others published stress corrosion cracking of welded joints of supermartensitic stainless steel in h 2 s free. Duplex stainless steel dss grades are used in pulp mills for their superior properties and resistance to general corrosion. Stainless steels are more resistant to general corrosion compared with carbon steel. Development of stress corrosion cracking resistant welds.
Welding may worsen the stress corrosion cracking susceptibility of the material. Welding of austenitic stainless steels grades ansi 304 and 316 results in sensitized microstructure and residual tensile stress in the heat affected zone haz making the material susceptible to intergranular stress corrosion cracking. This cracking was found first in piping and then became a significant issue for reactor pressure vessel rpv internals. These cracks are not visible initially, but as time passes, these individual cracks may grow and forms colonies, and many of them join together to form longer cracks. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Understanding and avoiding intergranular stress corrosion cracking of welded supermartensitic stainless steel.
The weld toe of the welded steel pipe is easy to form stress corrosion crack. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Corrosionpedia causes and prevention of corrosion on. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. When you heat austenitic stainless steel at around 450 to 850 degrees celsius, the carbon in the steel converts to grain boundaries which lead to corrosion. Effect of weld metal chemistry on stress corrosion. The micrograph below x300 illustrates scc in a 316 stainless steel chemical processing piping system. The eddy current array system used by the magnaform scanner from olympus eliminates surface preparation. Stress corrosion cracking susceptibility of 304l substrate. Pitting and stress corrosion cracking behavior in welded. Penetrant testing to inspect rough, dirty, or painted stainless steel pipes for stress corrosion cracking and welds for cracks can be slow because of surface preparation before and after inspection. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning.
Stress corrosion cracking occurs in many different materials, in the presence of different corrosive media, but it is especially prevalent in austenitic stainless steels in the presence of. Chloride stress corrosion cracking is the most likely life limiting failure with austenitic stainless steel tubing. Specific corrosion types are galvanic, stress corrosion, hydrogen cracking, intergranular and pitting corrosion. Heat exchanger tubes of aisi 321 ss, welded either by a laser beam welding lbw or by b metal inert gas welding mig were used for the study. Application of more productive joining process for dissimilar welds like submerged arcwelding instead of currently employed gas metal. Welding is one of the most common types of metal fabrication. Corrosion resistance of stainless steels and welding. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Stress corrosion cracking susceptibility of super 304h parent metal and gas tungsten arc gta welded joints were studied by constant load tests in. Corrosion behavior of welded stainless steel corrosion resistance of stainless steel weld metal depends on an understanding of the nature of the protective passive film that gives the steel its stainless characteristic by t. Intergranular stress corrosion cracking of welded steel twi.
Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Pdf stress corrosion cracking of welded joints of supermartensitic. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic. Recent experiences with duplex 2205 stainless steel welds have shown that stress corrosion cracking can occur which may lead tocatastrophic failures. Stress corrosion cracking in wholly austenitic type 304 base metal occurs transgranularly, while cracking in duplex weld metal occurs either by the combined action of stress assisted ferrite dissolution and stress corrosion cracking scc in the austenite or entirely by stress assisted dissolution of the ferrite. Pitting and stress corrosion cracking behavior in welded austenitic. The effect of welding residual stress for making artificial stress. To simulate the microstructure of a core shroud horizontal weld, mockup sma welds were prepared from the steel plates. Stress corrosion cracking in pipelines begins when small cracks develop on the external surface of buried pipelines. Stress corrosion cracking of austenitic stainless steel. Effect of welding conditions on residual stress and stress. Scc in a 316 stainless steel chemical processing piping system. Stresscorrosioncracking, a dangerous service condition. Chlorideinduced stress corrosion cracking ciscc of welded zones is of special concern, as it a welldocumented mode of attack for austenitic stainless steels marine environments, and many independent spent fuel storage installations isfsis are located in coastal areas.
Stress corrosion cracking of welded 2205 duplex stainless steel in. Stress corrosion cracking behaviour of gas tungsten arc. Effect of weld metal chemistry on stress corrosion cracking. Reactors bwrs experienced intergranular stress corrosion cracking igscc in austenitic stainless steel during this time. Chloride stress corrosion cracking in austenitic stainless. Stress corrosion cracking in dissimilar metal welds with. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Weld decay and intergranular corrosion causes and prevention. Stress corrosion cracking of ferritic steel weld metal. Paper presented at corrosion 2007, paper 07094, nashville, tennessee, 11. Faster inspections of welds and stress corrosion cracking.
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